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21.
Rui Galhano dos Santos Noemi F. Acero Sandro Matos Ricardo Carvalho Mário Vale Ana C. Marques João C. Bordado Maria M. Mateus 《Journal of Polymers and the Environment》2018,26(1):91-100
The use of petroleum-derived products should be avoided regarding the principles of green and sustainable chemistry. The work reported herein, is aimed at the liquefaction of pine shavings for the production of an environmentally-friendly polyol suitable to be used in the formulations of sprayable polyurethane foams. The biopolyols were obtained in high yield and were used to replace those derived from fossil sources, to produce more “greener” polyurethane foams and therefore, less dependent on petroleum sources, since the polyol component was substituted by products resulting from biomass liquefaction. The partial and fully exchange of the polyols was accomplished, and the results compared with a reference foam. The foams were afterward, chemical, physical, morphological, and mechanically characterized. The complete replacement of polyether polyol and polyol polyester has presented some similar characteristics as that used as a reference, validating that the path chosen for the development of more sustainable materials is on the right track for the contribution to a cleaner world. 相似文献
22.
Kannan Rassiah M. M. H. Megat Ahmad Aidy Ali Abd Halid Abdullah Sasitharan Nagapan 《Journal of Polymers and the Environment》2018,26(4):1328-1342
This study investigated the application of bamboo as a natural composite, in which its potential as a composite material had been examined for 2–6 layers. In precise, the woven bamboo (BW) formed the culm fiber composite with an average of 0.5 mm thickness and 5.0 mm width strip. In addition, this study looked into a specific type of bamboo species known as Gigantochloa Scortechinii (Buluh Semantan), which can be found in Malaysia. This laminated plain BW, which had been reinforced with epoxy (EP), was developed by applying the hand lay-up technique. After that, the specimens were characterized via mechanical analyses, for instance, tensile, flexural, hardness, and impact tests. As a result, the 2-layer BW had displayed rather excellent results chiefly due to the incorporation of epoxy composite, although this is exceptional hardness value. 相似文献
23.
Thomas Minning Darren A. Lytle Maily Pham Keith Kelty 《Environmental monitoring and assessment》2015,187(6):383
Distinguishing between soluble and particulate lead in drinking water is useful in understanding the mechanism of lead release and identifying remedial action. Typically, particulate lead is defined as the amount of lead removed by a 0.45-μm filter. Unfortunately, there is little guidance regarding selection of filter membrane material and little consideration to the possibility of the sorption of dissolved lead to the filter. The objective of this work was to examine the tendency of 0.45-μm syringe filter materials to adsorb lead. Tests were performed with water containing 40 and 24 μg/L soluble lead at pH 7 buffered with 50 mg C/L dissolved inorganic concentration (DIC). The amounts of lead sorbed greatly varied by filter, and only two filter types, polypropylene and mixed cellulose esters, performed well and are recommended. Great care must be taken in choosing a filter when filtering soluble lead and interpreting filter results. 相似文献
24.
V. Vijayasree Hebsy Bai S. Naseema Beevi Thomas Biju Mathew Thomas George George Xavier 《Environmental monitoring and assessment》2015,187(5):299
Dissipation and decontamination of chlorantraniliprole (Coragen 18.5 SC) in brinjal and okra fruits were studied following field application at single and double doses of 30 and 60 g ai ha?1, and the residues of the insecticide was estimated using LC-MS/MS. Initial residues of chlorantraniliprole at single and double doses on the fruits of brinjal were 0.72 and 1.48 mg kg?1, while on okra fruits, the residues were 0.48 and 0.91 mg kg?1, respectively. The residues reached below detectable level of 0.01 mg kg?1 on the 10th day. Half-life of chlorantraniliprole at 30 and 60 g ai ha?1 on brinjal was 1.58 and 1.80 days with the calculated waiting period of 0.69 and 2.38 days, whereas on okra, the values were 1.60 and 1.70 and 0 and 1.20 days, respectively. The extent of removal of chlorantraniliprole using simple decontaminating techniques at 2 h and 3 days after spraying was 40.99–91.37 % and 29.85–89.12 %, respectively, from brinjal fruits and 47.78–86.10 % and 41.77–86.48 %, respectively, from okra fruits. 相似文献
25.
William D. Klaren David Vine Stefan Vogt Larry W. Robertson 《Environmental science and pollution research international》2018,25(17):16427-16433
Animal studies show that exposure to the environmental pollutant 3,3′,4,4′,5-pentachlorobiphenyl (PCB126) causes alterations in hepatic metals as measured in acid-digested volume-adjusted tissue. These studies lack the detail of the spatial distribution within the liver. Here we use X-ray fluorescence microscopy (XFM) to assess the spatial distribution of trace elements within liver tissue. Liver samples from male Sprague Dawley rats, treated either with vehicle or PCB126, were formalin fixed and paraffin embedded. Serial sections were prepared for traditional H&E staining or placed on silicon nitride windows for XFM. With XFM, metal gradients between the portal triad and the central vein were seen, especially with copper and iron. These gradients change with exposure to PCB126, even reverse. This is the first report of how micronutrients vary spatially within the liver and how they change in response to toxicant exposure. In addition, high concentrations of zinc clusters were discovered in the extracellular space. PCB126 treatment did not affect their presence, but did alter their elemental makeup suggesting a more general biological function. Further work is needed to properly evaluate the gradients and their alterations as well as classify the zinc clusters to determine their role in liver function and zinc homeostasis. 相似文献
26.
Anders Mosbech Kasper Lambert Johansen Thomas A. Davidson Martin Appelt Bjarne Grønnow Christine Cuyler Peter Lyngs Janne Flora 《Ambio》2018,47(2):226-243
The little auk is the most numerous seabird in the North Atlantic and its most important breeding area is the eastern shores of the North Water polynya. Here, a population of an estimated 33 million pairs breeds in huge colonies and significantly shapes the ecosystem. Archaeological remains in the colonies document that the little auk has been harvested over millennia. Anthropological research discloses how the little auk has a role both as social engineer and as a significant resource for the Inughuit today. The hunting can be practiced without costly equipment, and has no gender and age discrimination in contrast to the dominant hunt for marine mammals. Little auks are ecological engineers in the sense that they transport vast amounts of nutrients from sea to land, where the nutrients are deposited as guano. Here, the fertilized vegetation provides important foraging opportunities for hares, geese, fox, reindeer, and the introduced muskox. We estimate that the relative muskox density is ten times higher within 1 km of little auk fertilized vegetation hotspots. 相似文献
27.
Pastoralists face increasing competition for land with crop farmers and nature in and around the W Biosphere Reserve (WBR) in Benin. Our aim was to describe and analyse land use changes in order to understand their drivers, and to describe and analyse the viewpoints of relevant stakeholders in order to understand the competition for land. To this end, remote sensing data, regional statistics, and survey data were collected. We found that crop land expansion around the WBR was the direct driver of decrease of the grazing land area. Population growth and rising demand for food crops, and government support to the cotton sector were indirect drivers of grazing land reduction. Furthermore, competing claims on land among users arose from the complex interaction of crop expansion, presence of WBR and the way it is governed, the lack of support to pastoralists, and the increasing shift of pastoralists’ lifestyle into one of settled crop farmers. Pastoralism is under threat and its survival depends on the successful implementation of policies to support pastoralists and protect grazing lands. 相似文献
28.
Kumar A Baroth A Soni I Bhatnagar P John PJ 《Environmental monitoring and assessment》2006,116(1-3):1-7
Anupgarh is the most fertile area of Rajasthan state where a variety of seasonal crops are grown. The availability of three
manmade canals has enhanced the agricultural activities in this area. The farmers use huge amounts of pesticides to increase
the crop productivity. Exposure of humans to these hazardous chemicals occurs directly in the fields and indirectly due to
consumption of contaminated diet, or by inhalation or by dermal contact. The organochlorine pesticides are reported to be
lipophilic and their presence in human milk and blood has been documented in different parts of the world. Blood and milk
samples were collected from lactating women who were divided into four groups on the basis of different living standards viz
residence area, dietary habits, working conditions and addiction to tobacco. The level of total organochlorine pesticides
in blood ranged from 3.319mg/L—6.253mg/L while in milk samples it ranged from 3.209Mdash;4.608 mg/L. The results are in concurrence
with the reports from other countries. 相似文献
29.
30.
A transition zone in the otoliths of orange roughy (Hoplostethus atlanticus) is described where annulus width decreases markedly. For fish sampled at spawning time, the relationship between gonad stage
and the presence or absence of a transition zone is consistent with the hypothesis that this zone marks the onset of maturity,
if allowance is made for some error in gonad staging and identification of the zone. Another data set from a non-spawning
area after the spawning season is not consistent with the hypothesis. However, these latter data are considered less reliable
because of the small size of the fish in the sample and difficulties in determining, outside the spawning season, whether
a fish has been reproductively active. This hypothesis was used to provide estimates of the median age (30 yr) and length
(31 cm) at the onset of maturity for the Chatham Rise, New Zealand population. These estimates are unaffected by the biases
associated with the usual ogive method of estimation.
Received: 27 June 1997 / Accepted: 1 July 1997 相似文献